OK - sorry for the late response - been working 13 hours, and haven't been around my PC.....

so - looks like the boot sector for the OS is in that 200mb partition, if you take a look at the screen shots looks like it couldn't boot from that windows partition.

I went ahead and switched it back to boot - and everything is "normal"

I took a screen shot of the error message (little triangle next to SDA3)

Let me know what you think